Valencia v Olympiakos, 12 September 2000
| Score | 2-1 to Valencia |
| Competition | UEFA Champions League Group C |
| Venue | Estadio Mestalla, Valencia |
| Attendance | 44,000 |
2 Valencia
Goals:
| Rubén Baraja | 36 |
|
|
| Diego Alonso | 45 |
|
Starting lineup:
Goalkeeper
Cañizares
Defender
Amedeo Carboni
Defender
Miroslav Dukić
Defender/Centre back
Mauricio Pellegrino
Full back
Jocelyn Angloma
Midfielder
Didier Deschamps
Midfielder
Cristian Alberto Kily Gonzalez
Midfielder
Mendieta
Midfielder
Rubén Baraja
Midfielder
Zlatko Zahovič
Forward
Diego Alonso
Substitutions:
| Juan Sanchez for Zlatko Zahovič | 66 |
| John Carew for Diego Alonso | 86 |
Cards:
| Cristian Alberto Kily Gonzalez | 26 | Y |
| Mendieta | 52 | Y |
1 Olympiakos
Goals:
| Predrag Dorđević | 74 |
|
Starting lineup:
Dimitrios Eleftheropoulos
Goalkeeper
Yeorgios Amanatidis
Defender
Dimitrios Mavrogenidis
Defender
Christos Patsatzoglou
Defender
Ilias Poursanidis
Defender
Predrag Dorđević
Midfielder
Christos Kontis
Midfielder
Moedim Junior José Elias Ze Elias
Midfielder
Par Zetterberg
Midfielder
Giovanni
Midfielder/Forward
De Souza Luciano
Midfielder/Forward
Substitutions:
| Peter Ofori-Quaye for Dimitrios Mavrogenidis | 73 |
| Stelios Giannakopoulos for Ilias Poursanidis | 85 |
| Lambros Choutos for De Souza Luciano | 90 |
Cards:
| Dimitrios Mavrogenidis | 11 | Y |
| Moedim Junior José Elias Ze Elias | 38 | Y |
| Yeorgios Amanatidis | 45 | Y |
| Ilias Poursanidis | 82 | Y |