Olympiakos v Valencia, 25 October 2000
| Score | 1-0 to Olympiakos |
| Competition | UEFA Champions League Group C |
| Venue | Spiros Louis, Athens |
| Attendance | 58,000 |
1 Olympiakos
Goals:
| Predrag Dorđević | penalty | 65 |
|
Starting lineup:
Goalkeeper
Dimitrios Eleftheropoulos
Defender
Yeorgios Amanatidis
Defender
Christos Patsatzoglou
Midfielder
Predrag Dorđević
Midfielder
Grigoris Georgatos
Midfielder
Christos Kontis
Midfielder
Moedim Junior José Elias Ze Elias
Midfielder
Par Zetterberg
Midfielder/Forward
Giovanni
Midfielder/Forward
De Souza Luciano
Forward
Lambros Choutos
Substitutions:
| Stelios Giannakopoulos for De Souza Luciano | 59 |
| Alexios Alexandris for Grigoris Georgatos | 59 |
| Georgos Anatolakis for Lambros Choutos | 74 |
Cards:
| Moedim Junior José Elias Ze Elias | 94 | Y |
On the bench:
Defender
Georgos Anatolakis
Midfielder
Stelios Giannakopoulos
Forward
Alexios Alexandris
0 Valencia
Goals:
Starting lineup:
Cañizares
Goalkeeper
Amedeo Carboni
Defender
Miroslav Dukić
Defender
Mauricio Pellegrino
Defender/Centre back
Albelda
Midfielder
Didier Deschamps
Midfielder
Garcia Leon Gerardo
Midfielder
Libero Parri
Midfielder
Vicente
Midfielder
Angulo
Forward
Diego Alonso
Forward
Substitutions:
| Luis Milla for Albelda | 49 |
| John Carew for Diego Alonso | 66 |
| Jocelyn Angloma for Libero Parri | 80 |
Cards:
| Diego Alonso | 29 | Y |
| Mauricio Pellegrino | 31 | Y |