Villarreal v Valencia, 23 January 2005
| Score | 3-1 to Villarreal |
| Referee | Losantos Omar |
| Competition | Primera Liga 20 |
| Venue | Estadio El Madrigal, Villarreal |
| Attendance | 20,000 |
3 Villarreal
Goals:
| Román Riquelme | penalty | 17 |
|
| Román Riquelme | 45 |
|
|
| Román Riquelme | penalty | 90 |
|
Starting lineup:
Goalkeeper
Pepe Reina
Defender
Rodolfo Arruabarena
Defender
Javi Venta
Defender
Juan Manuel Pena
Defender
Gonzalo Rodriguez
Midfielder
Romero Hector Font
Midfielder
Moreno Josico
Midfielder
Marcos Senna
Midfielder
Román Riquelme
Forward
Diego Forlán
Forward
Antonio Guayre
Substitutions:
| Juan Pablo Sorin for Romero Hector Font | 63 |
| Romero Poyon Jose Mari for Antonio Guayre | 71 |
| Santi Cazorla for Diego Forlán | 89 |
Cards:
| Gonzalo Rodriguez | Y | |
| Moreno Josico | Y | |
| Juan Manuel Pena | Y | |
| Marcos Senna | Y | |
| Gonzalo Rodriguez | R |
On the bench:
1 Valencia
Goals:
| Pablo Aimar | penalty | 89 |
|
Starting lineup:
Cañizares
Goalkeeper
Amedeo Carboni
Defender
Marchena
Defender
Marco Caneira
Defender
Emiliano Moretti
Defender
Roberto Ayala
Defender/Centre back
Pablo Aimar
Midfielder
Albelda
Midfielder
Stefano Fiore
Midfielder
Francisco Joaquin Rufete
Midfielder
Miguel Mista
Forward
Substitutions:
| Juan Luis Hens Lorite Juanlu for Francisco Joaquin Rufete | 8 |
| Marco Di Vaio for Juan Luis Hens Lorite Juanlu | 46 |
| Andres Palop for Cañizares | 63 |
Cards:
| Marchena | Y | |
| Cañizares | Y | |
| Marco Caneira | Y |