Valencia v Villarreal, 25 February 2001
| Score | 3-1 to Valencia |
| Competition | Primera Liga 24 |
| Venue | Estadio Mestalla, Valencia |
| Attendance | 53,000 |
3 Valencia
Goals:
| John Carew | 18 |
|
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| John Carew | 47 |
|
|
| John Carew | 83 |
|
Starting lineup:
Goalkeeper
Cañizares
Defender
Miroslav Dukić
Defender/Centre back
Roberto Ayala
Defender/Centre back
Mauricio Pellegrino
Full back
Jocelyn Angloma
Midfielder
Pablo Aimar
Midfielder
Cristian Alberto Kily Gonzalez
Midfielder
Mendieta
Midfielder
Rubén Baraja
Forward
John Carew
Forward
Juan Sanchez
Substitutions:
| Albelda for Mendieta | 82 |
| Vicente for Cristian Alberto Kily Gonzalez | 85 |
Cards:
| Mauricio Pellegrino | Y | |
| Juan Sanchez | Y |
1 Villarreal
Goals:
| Sanjuan Quique Alvarez | 34 |
|
Starting lineup:
Javier Lopez Vallejo
Goalkeeper
Rodolfo Arruabarena
Defender
Jesus Galvan
Defender
Sanjuan Quique Alvarez
Defender
Vergara Diaz Caballero Unai
Defender
Amor
Midfielder
Diego Cagna
Midfielder
Javi Gracia
Midfielder
Montana Jorge Lopez
Midfielder
Martin Palermo
Forward
Substitutions:
| Jose Ignacio Berruet for Vergara Diaz Caballero Unai | 67 |
| Xavier Roca for Javi Gracia | 74 |
| Gheorghe Craioveanu for Montana Jorge Lopez | 74 |
Cards:
| Manuel Fernandez Gutierrez Victor | 62 | Y |
| Gheorghe Craioveanu | 77 | Y |