Napoli v Villarreal, 27 September 2011
| Score | 2-0 to Napoli |
| Referee | Frank De Bleeckere |
| Competition | UEFA Champions League Group A |
| Venue | San Paolo, Naples |
| Attendance | 46,747 |
2 Napoli
Manager: Walter Mazzarri
Goals:
| Marek Hamšík | 15 |
|
|
| Edinson Cavani | penalty | 17 |
|
Starting lineup:
Goalkeeper
Morgan De Sanctis
Defender
Salvatore Aronica
Defender
Hugo Campagnaro
Defender
Paolo Cannavaro
(captain)
Defender
Andrea Dossena
Defender/Midfielder
Camilo Zúñiga
Midfielder
Walter Gargano
Midfielder
Gokhan Inler
Midfielder
Marek Hamšík
Forward
Edinson Cavani
Forward
Ezequiel Lavezzi
Substitutions:
| Goran Pandev for Edinson Cavani | 71 |
| Giuseppe Mascara for Marek Hamšík | 79 |
| Mario Santana for Ezequiel Lavezzi | 88 |
Cards:
| Salvatore Aronica | 5 | Y |
| Paolo Cannavaro | 57 | Y |
On the bench:
Goalkeeper
Antonio Rosati
Defender
Federico Fernández
Defender
Ignacio Fideleff
Defender
Gianluca Grava
Midfielder
Mario Santana
Forward
Giuseppe Mascara
Forward
Goran Pandev
0 Villarreal
Manager: Juan Carlos Garrido
Goals:
Starting lineup:
Diego Lopez
Goalkeeper
Jose Catala
Defender
Mateo Musacchio
Defender
Gonzalo Rodriguez
Defender
Cristián Zapata
Defender
Bruno Soriano
Midfielder
Cani
Midfielder
Jonathan De Guzman
Midfielder
Marcos Senna
Midfielder
(captain)
Giuseppe Rossi
Midfielder
Nilmar
Forward
Substitutions:
| Javier Camunas for Gonzalo Rodriguez | 33 |
| Mubarak Wakaso for Marcos Senna | 84 |
| Hernán Pérez for Jonathan De Guzman | 84 |
Cards:
| Gonzalo Rodriguez | 16 | Y |
| Cani | 85 | Y |
| Giuseppe Rossi | 85 | Y |
On the bench:
Goalkeeper
César
Defender
Marchena
Defender
Mario
Defender
Joan Oriol
Midfielder
Hernán Pérez
Midfielder
Mubarak Wakaso
Midfielder/Forward
Javier Camunas