PSV Eindhoven v Union St Gilloise, 16 September 2025
| Score | 3-1 to Union St Gilloise |
| Referee | Anthony Taylor |
| Competition | UEFA Champions League League phase |
| Venue | Philips Stadion, Eindhoven |
| Attendance | 35,000 |
Kick-off: 6.45pm local
1 PSV Eindhoven
Manager: Peter Bosz
3 Union St Gilloise
Manager: Sebastien Pocognoli