PSV Eindhoven v Napoli, 21 October 2025
| Score | 6-2 to PSV Eindhoven |
| Referee | Daniel Siebert |
| Competition | UEFA Champions League League phase |
| Venue | Philips Stadion, Eindhoven |
| Attendance | 34,700 |
Kick-off: 9.00pm local
6 PSV Eindhoven
Manager: Peter Bosz
2 Napoli
Manager: Antonio Conte