PSV Eindhoven v Napoli, 04 October 2012
| Score | 3-0 to PSV Eindhoven |
| Referee | Alexandru Dan Tudor |
| Competition | UEFA Europa League Group F |
| Venue | Philips Stadium, Eindhoven |
| Attendance | 18,200 |
3 PSV Eindhoven
Manager: Dick Advocaat
Starting lineup:
Substitutions:
Cards:
On the bench:
0 Napoli
Manager: Walter Mazzarri
Starting lineup:
Antonio Rosati
Goalkeeper
Salvatore Aronica
Defender
Paolo Cannavaro
Defender
(captain)
Andrea Dossena
Defender
Federico Fernández
Defender
Marco Donadel
Midfielder
Blerim Dzemaili
Midfielder
Omar El Kaddouri
Midfielder
Giandomenico Mesto
Midfielder
Lorenzo Insigne
Forward
Eduardo Vargas
Forward
Substitutions:
| Edinson Cavani for Omar El Kaddouri | 46 |
| Goran Pandev for Lorenzo Insigne | 62 |
| Camilo Zúñiga for Andrea Dossena | 72 |
Cards:
| Omar El Kaddouri | 2 | Y |
| Andrea Dossena | 48 | Y |
| Federico Fernández | 57 | Y |
| Paolo Cannavaro | 84 | Y |
| Giandomenico Mesto | 86 | Y |
| Goran Pandev | 86 | Y |
| Edinson Cavani | 88 | Y |
| Salvatore Aronica | 90 | Y |
On the bench:
Goalkeeper
Morgan De Sanctis
Defender
Hugo Campagnaro
Defender/Midfielder
Valon Behrami
Defender/Midfielder
Camilo Zúñiga
Midfielder
Gokhan Inler
Forward
Edinson Cavani
Forward
Goran Pandev