PSV Eindhoven v Benfica, 24 August 2021
| Score | 0-0 |
| Competition | UEFA Champions League Play-off 2nd leg |
| Venue | Philips Stadium, Eindhoven |
| Attendance | 21,855 |
Kick-off: 9.00pm local
Benfica won 2-1 on aggregate
| Score | 0-0 |
| Competition | UEFA Champions League Play-off 2nd leg |
| Venue | Philips Stadium, Eindhoven |
| Attendance | 21,855 |