Olympiakos v Atletico Madrid, 16 September 2014
| Score | 3-2 to Olympiakos |
| Referee | Pedro Proenca |
| Competition | UEFA Champions League Group A |
| Venue | Georgios Karaiskakis Stadium, Athens |
| Attendance | 31,846 |
Kick-off: 9.45pm local (7.45pm BST)
3 Olympiakos
Manager: Michel
2 Atletico Madrid
Manager: German Burgos