Napoli v PSV Eindhoven, 06 December 2012
| Score | 3-1 to PSV Eindhoven |
| Referee | Mike Dean |
| Competition | UEFA Europa League Group F |
| Venue | San Paolo, Naples |
| Attendance | 7,000 |
1 Napoli
Manager: Walter Mazzarri
Goals:
| Edinson Cavani | 18 |
|
Starting lineup:
Goalkeeper
Antonio Rosati
Defender
Bruno Uvini
Defender
Hugo Campagnaro
Defender
Andrea Dossena
Defender
Federico Fernández
Defender
Christian Maggio
(captain)
Midfielder
Marco Donadel
Midfielder
Omar El Kaddouri
Midfielder
Gokhan Inler
Forward
Edinson Cavani
Forward
Eduardo Vargas
Substitutions:
| Goran Pandev for Gokhan Inler | 57 |
| Roberto Insigne for Edinson Cavani | 66 |
| Giandomenico Mesto for Christian Maggio | 69 |
Cards:
| Hugo Campagnaro | 71 | Y |
On the bench:
Goalkeeper
Morgan De Sanctis
Defender
Alessandro Gamberini
Defender/Midfielder
Valon Behrami
Midfielder
Giandomenico Mesto
Midfielder/Forward
Giuseppe Fornito
Forward
Roberto Insigne
Forward
Goran Pandev
3 PSV Eindhoven
Manager: Dick Advocaat