Napoli v Borussia Dortmund, 18 September 2013
| Score | 2-1 to Napoli |
| Referee | Pedro Proenca |
| Competition | UEFA Champions League Group F |
| Venue | San Paolo, Naples |
| Attendance | 55,766 |
Kick-off: 8.45pm local (7.45pm BST)
2 Napoli
Manager: Rafael Benitez
Goals:
| Gonzalo Higuaín | 29 |
|
|
| Lorenzo Insigne | 67 |
|
Starting lineup:
Goalkeeper
Pepe Reina
Defender
Miguel Britos
Defender
Christian Maggio
Defender/Midfielder
Valon Behrami
Defender/Midfielder
Camilo Zúñiga
Midfielder
José Callejón
Midfielder
Gokhan Inler
Midfielder
Marek Hamšík
(captain)
Midfielder
Raúl Albiol
Forward
Gonzalo Higuaín
Forward
Lorenzo Insigne
Substitutions:
| Dries Mertens for Lorenzo Insigne | 73 |
| Goran Pandev for Gonzalo Higuaín | 78 |
| Giandomenico Mesto for Marek Hamšík | 90 |
Cards:
| Valon Behrami | 33 | Y |
| Miguel Britos | 36 | Y |
| Lorenzo Insigne | 68 | Y |
On the bench:
Goalkeeper
Rafael
Defender
Pablo Armero
Defender
Paolo Cannavaro
Midfielder
Blerim Dzemaili
Midfielder
Giandomenico Mesto
Forward
Dries Mertens
Forward
Goran Pandev
1 Borussia Dortmund
Manager: Jurgen Klopp
Goals:
| Camilo Zúñiga | own goal | 87 |
|
Starting lineup:
Roman Weidenfeller
Goalkeeper
(captain)
Mats Hummels
Defender
Marcel Schmelzer
Defender
Neven Subotić
Defender
Sven Bender
Midfielder
Jakub Błaszczykowski
Midfielder
Henrikh Mkhitaryan
Midfielder
Nuri Şahin
Midfielder
Marco Reus
Midfielder/Forward
Kevin Grosskreutz
Forward
Robert Lewandowski
Forward
Substitutions:
| Pierre-Emerick Aubameyang for Mats Hummels | 45 |
| Mitchell Langerak for Jakub Błaszczykowski | 45 |
| Jonas Hofmann for Henrikh Mkhitaryan | 76 |
Cards:
| Marcel Schmelzer | 39 | Y |
| Roman Weidenfeller | 45 | R |
On the bench:
Goalkeeper
Mitchell Langerak
Defender
Koray Gunter
Midfielder
Erik Durm
Midfielder
Jonas Hofmann
Midfielder
Oliver Kirch
Forward
Pierre-Emerick Aubameyang
Forward
Julian Schieber