Napoli v Borussia Dortmund, 18 September 2013
| Score | 2-1 to Napoli |
| Referee | Pedro Proenca |
| Competition | UEFA Champions League Group F |
| Venue | San Paolo, Naples |
| Attendance | 55,766 |
Kick-off: 8.45pm local (7.45pm BST)
2 Napoli
Manager: Rafael Benitez
Goals:
| Gonzalo Higuaín | 29 |
|
|
| Lorenzo Insigne | 67 |
|
Starting lineup:
Goalkeeper
Pepe Reina
Defender
Miguel Britos
Defender
Christian Maggio
Defender/Midfielder
Valon Behrami
Defender/Midfielder
Camilo Zúñiga
Midfielder
José Callejón
Midfielder
Gokhan Inler
Midfielder
Marek Hamšík
(captain)
Midfielder
Raúl Albiol
Forward
Gonzalo Higuaín
Forward
Lorenzo Insigne
Substitutions:
| Dries Mertens for Lorenzo Insigne | 73 |
| Goran Pandev for Gonzalo Higuaín | 78 |
| Giandomenico Mesto for Marek Hamšík | 90 |
Cards:
| Valon Behrami | 33 | Y |
| Miguel Britos | 36 | Y |
| Lorenzo Insigne | 68 | Y |
On the bench:
Goalkeeper
Rafael
Defender
Pablo Armero
Defender
Paolo Cannavaro
Midfielder
Blerim Dzemaili
Midfielder
Giandomenico Mesto
Forward
Dries Mertens
Forward
Goran Pandev
1 Borussia Dortmund
Manager: Jurgen Klopp
Goals:
| Camilo Zúñiga | own goal | 87 |
|
Starting lineup:
Roman Weidenfeller
Goalkeeper
(captain)
Mats Hummels
Defender
Marcel Schmelzer
Defender
Neven Subotić
Defender
Sven Bender
Midfielder
Jakub Błaszczykowski
Midfielder
Henrikh Mkhitaryan
Midfielder
Nuri Şahin
Midfielder
Marco Reus
Midfielder
Kevin Grosskreutz
Forward
Robert Lewandowski
Forward
Substitutions:
| Pierre-Emerick Aubameyang for Mats Hummels | 45 |
| Mitchell Langerak for Jakub Błaszczykowski | 45 |
| Jonas Hofmann for Henrikh Mkhitaryan | 76 |
Cards:
| Marcel Schmelzer | 39 | Y |
| Roman Weidenfeller | 45 | R |
On the bench:
Goalkeeper
Mitchell Langerak
Defender
Koray Gunter
Midfielder
Erik Durm
Midfielder
Jonas Hofmann
Midfielder
Oliver Kirch
Forward
Pierre-Emerick Aubameyang
Forward
Julian Schieber