Barcelona v Villarreal, 12 November 2000
| Score | 2-1 to Villarreal |
| Competition | Primera Liga 10 |
| Venue | Camp Nou, Barcelona |
| Attendance | 60,000 |
1 Barcelona
Goals:
| Phillip Cocu | 20 |
|
Starting lineup:
Goalkeeper
Francesc Arnau
Defender
Abelardo
Defender
Puyol
Defender
Sergi
Midfielder
Phillip Cocu
Midfielder
Luis Enrique
Midfielder
Emmanuel Petit
Midfielder
Simão
Midfielder
Xavi
Forward
Perez Munoz Alfonso
Forward
Patrick Kluivert
Substitutions:
| Dani García for Perez Munoz Alfonso | 60 |
| Gerard for Puyol | 61 |
| Marc Overmars for Sergi | 70 |
Cards:
| Phillip Cocu | 67 | Y |
| Luis Enrique | 67 | Y |
| Xavi | 67 | Y |
| Abelardo | 80 | Y |
2 Villarreal
Goals:
| Manuel Fernandez Gutierrez Victor | 1 |
|
|
| Manuel Fernandez Gutierrez Victor | 57 |
|
Starting lineup:
Jesús Unanua
Goalkeeper
Rodolfo Arruabarena
Defender
Jose Ignacio Berruet
Defender
Ortega Quique Medina
Defender
Xavier Roca
Defender
Vergara Diaz Caballero Unai
Defender
Amor
Midfielder
Diego Cagna
Midfielder
Javi Gracia
Midfielder
Bruno Marioni
Forward
Substitutions:
| Gheorghe Craioveanu for Bruno Marioni | 71 |
| Gerard Escoda for Amor | 78 |
Cards:
| Ortega Quique Medina | 16 | Y |
| Jose Ignacio Berruet | 17 | Y |
| Vergara Diaz Caballero Unai | 19 | Y |
| Manuel Fernandez Gutierrez Victor | 29 | Y |
| Jesús Unanua | 31 | Y |
| Amor | 68 | Y |
| Xavier Roca | 81 | Y |
| Javi Gracia | 88 | Y |
| Gerard Escoda | 91 | Y |
| Gheorghe Craioveanu | 93 | Y |