Barcelona v Ajax, 18 September 2013
| Score | 4-0 to Barcelona |
| Referee | Svein Oddvar Moen |
| Competition | UEFA Champions League Group H |
| Venue | Camp Nou, Barcelona |
| Attendance | 79,412 |
Kick-off: 8.45pm local (7.45pm BST)
4 Barcelona
Manager: Gerardo Martino
Goals:
| Lionel Messi | 22 |
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| Lionel Messi | 55 |
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| Gerard Piqué | 69 |
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| Lionel Messi | 75 |
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Starting lineup:
Goalkeeper
Victor Valdés
(captain)
Defender
Dani Alves
Defender
Gerard Piqué
Defender/Midfielder
Javier Mascherano
Midfielder
Adriano Correia
Midfielder
Cesc Fàbregas
Midfielder
Iniesta
Midfielder
Sergio Busquets
Midfielder/Forward
Lionel Messi
Midfielder/Forward
Alexis Sánchez
Forward
Neymar
Substitutions:
| Xavi for Cesc Fàbregas | 71 |
| Pedro for Neymar | 72 |
| Marc Bartra for Gerard Piqué | 80 |
On the bench:
Goalkeeper
Jose Manuel Pinto
Defender
Marc Bartra
Defender
Martín Montoya
Defender/Midfielder
Alex Song
Midfielder
Pedro
Midfielder
Xavi
Forward
Cristian Tello
0 Ajax
Manager: Frank de Boer